The Platters - My Prayer 
I love the way doo-wop songs just grab your attention immediately with these incredible intros built to cut through the airwaves of their radio heyday to standout. This one is just another perfect example. To be honest, the song that follows is solid, but that intro ... loop it up and lock me in a listening room.
A note that I, and possibly I alone, find interesting: While the song has been featured in a few soundtracks over the years, its placement in David Lynch's "Twin Peaks: The Return" stands out to me. Partially, because I was obsessed with that show, but also because of in the depths of my research of understanding every facet of each episode, I learned that one of the singers in The Platters was also named David Lynch. In conclusion, David Lynch is weird and so I am and, y'know what, if you're reading this, you are too. Earth: A Big Bunch of Weirdos.